Polycyclic High-Density Cage Compounds via Cross Metathesis

Sambasivarao Kotha; Usha Nandan Chaurasia

doi:10.1055/a-2047-6742

Synthesis, Table of Contents

Synthesis 2023; 55(14): 2151-2158
DOI: 10.1055/a-2047-6742

paper

Polycyclic High-Density Cage Compounds via Cross Metathesis

Authors

Sambasivarao Kotha∗
Usha Nandan Chaurasia

Abstract

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Abstract

The synthesis of various highly functionalized caged systems suitable as high energy density materials, which were assembled by utilization of an olefin cross-metathesis strategy, is reported. E-Selectivity was observed during the cross-metathesis by using Grubbs second generation catalyst (G-II) and N-tolyl Grubbs catalyst in most of the cross-metathesis products. The stereochemistry of the olefin formed during the cross-metathesis has been determined unambiguously by a single-crystal X-ray diffraction study.

Key words

Cookson’s dione - Grignard addition - cross metathesis - cycloaddition - HEDMs

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